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Below are the steps to do the task..step 1: Click Start->All Programs->Accessories->Command Prompt.
step 2: Click Command Prompt This will open a DOS command window.
step 3: Type: notepad C:/Windows/System32/drivers/etc/hosts
step 4: Locate the line 127.0.0.1 localhost
step 5: To block the website orkut.com for example, just add this text under 127.0.0.1 localhost:
127.0.0.1 orkut.com
127.0.0.1 www.orkut.com
You can add as many sites any site, However you will need to prefix it with "127.0.0.1".
step 6: Save the file
Google will now be blocked in all web browser. This is an advanced but easy method on how to block a website.